Methyl formate CAS 107-31-3

CAS:107-31-3
MF:C2H4O2
MW:60.05
EINECS:203-481-7

MOQ (Minimum Order Quantity): 1 FCL (Full Container Load)

Product Details

Methyl formate CAS 107-31-3

Methyl formate is an ester derivative of formic acid, a colorless, transparent, and volatile liquid at room temperature. It has a pleasant aroma. It is soluble in water, alcohols, and ethers, and can also be saponified with water and alkali solutions. It is readily hydrolyzed in moisture. Its vapor forms an explosive mixture with air, with an explosion limit of 6.0%–20.0% (by volume). Methyl formate is an important raw material for organic synthesis, widely used in fragrances, solvents, organic synthesis, bactericides, and insecticides.

Melting point -100 °C (lit.)
Boiling point 32-34 °C (lit.)
density 0.974 g/mL at 20 °C (lit.)
vapor density 2.1 (vs air)
vapor pressure 32.91 psi ( 55 °C)
refractive index n20/D 1.343(lit.)
Fp −16 °F
storage temp. Store below +30°C.
solubility 300g/l, 25% soluble in water, miscible with alcohol, Propylene glycol, Glycerin and oils.
form Liquid
color Clear colorless
OdorPleasant; agreeable.
PH4-5 (200g/l, H2O, 20℃)
explosive limit5-23%(V)
Odor Threshold130ppm
Odor Typefruity
biological sourcesynthetic
Water Solubility 300 G/L (20 ºC)
Thermal Conductivity0.187 W/(m·K) at 25 ℃
λmaxλ: 259 nm Amax: 1.00
λ: 260 nm Amax: 0.70
λ: 265 nm Amax: 0.20
λ: 270 nm Amax: 0.04
λ: 310-400 nm Amax: 0.01
Merck 14,6077
BRN 1734623
Henry's Law Constant0.90 at 5.00 °C, 1.18 at 10.00 °C, 1.51 at 15.00 °C, 1.91 at 20.00 °C, 2.36 at 25.00 °C (column stripping-UV, Kutsuna et al., 2005)
Exposure limitsTLV-TWA 100 ppm (~250 mg/m3) (ACGIH, MSHA, and OSHA); TLV-STEL 150 ppm (~375 mg/m3) (ACGIH); IDLH 5000 ppm (NIOSH).
Dielectric constant8.5(20℃)
Stability:Stable. Extremely flammable. Readily forms explosive mixtures with air. Note low flash point and very wide explosion limits. Incompatible with oxidizing agents.
Major Applicationcleaning products
cosmetics
flavors and fragrances
food and beverages
personal care
InChI1S/C2H4O2/c1-4-2-3/h2H,1H3
InChIKeyTZIHFWKZFHZASV-UHFFFAOYSA-N
SMILES[H]C(=O)OC
LogP-0.21 at 25℃
CAS DataBase Reference107-31-3(CAS DataBase Reference)
NIST Chemistry ReferenceMethyl formate(107-31-3)
EPA Substance Registry SystemMethyl formate (107-31-3)

Product Application of CAS#107-31-3

It is used as a raw material for cellulose acetate and DMF, a solvent for the pesticide carbendazim, a curing agent in phenolic resins, and a fumigant for fruits and various types of tobacco.

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